Hello!
With de-cat you might see some marginal gains in the high-revs area, but even that is not for sure. Modern cats aren't really restrictive.
I'm not sure if 3.2 has a lambda-probe behind the cat -> if it has, then you will have a EML with decat.
On the other hand, you will loose some low-rev torque - this I can say for sure, because I was running decat pipes for years on a X30XE, and at the end placed a couple of mufflers on the position where the cats were -> there was a notticable better trottle response on low revs (1000-2500 rpms).
Also, in my experience, exhaust sound with decats is awful, especially on acceleration.
IMO, in generall, if you don't have knowledge and money, keep away from V6 exhaust modifications.
After all, the marginal gain on HP you might see from decat will really make little or no difference on the drifting abbility - just strip it of all unnecessary (to reduce weight), stiffen up suspension (springs, dampers, bushings), and weld the diff.
PS. As Kevin pointed out, exhaust manifold are really a bottle-neck for any usable exhaust tuning.