sorry, only just come to this....
glowing cats have two causes :-
first is a lean mixture, usually an inlet air leak, resulting in over-hot exhaust gas.
second is a large amount of unburnt fuel hitting an already-hot cat. obviously my favourite for this.
for that kind of fuel usage, you are probably beyond the damage that a bust lambda sensor could do, but you'll already need two new ones anyway.
I'd look at the fuel pressure regulator - it is possible for the diaphragm to burst, allowing pressurised fuel directly into the inlet manifold - that'd cause your problem.
next, look at lambda failure + coolant temp sensor failure, but this should be obvious from the datalog in the Motronic ECU.
regarding the fuel tank vent - there is only one and it's in the evap loss can under the wing - the rest of the system is sealed. With the engine OFF, the tank and the evap loss can are connected, allowing the vapour raised through heating the fuel in the tank on a hot day to be collected in the canister. With the engine ON, the putrge valve opens occasionally to allow the stored vapours to be drawn into the engine. ( it's the one above the breather box ). I would double check that the fuel tank is under pressure and not under vacuum. reason being that there isn't a ready source of pressure available to do this. Certainly fuel pressure couldn't cause a tank to become pressurised.
so, in conclusion....
replace the exhaust and all the lambda sensors.
check the fuel pressure regulator
check that all the sensors and vacuum lines are properly connected
make sure that the DIS pack is connected properly
check the fuel tank for splits / leaks