I've used optimax in a variety of vehicles and have always noticed some difference. It varies on the complexity of the engine management and or state of tune. My Cavalier 2lt ecotec, Senator 24v and a tuned Carb'ed motorbike were all faster, more urgent rev response, and returned better MPG. In the Senny it actualy cost me 4% more and returned 7% better economy (there abouts) so overall saved me money to use a more fun fuel.
It does take a full 2 tanks to see all the difference, give the ECU chance to adjust, dilute down the old fuel and a few miles to clean out the system.
So its hard to feel an 'instant' difference, as it happens gradually. What i do say to nay sayers, is put it in for two full tanks, then as you about to run out, take her out for a propper taz around, then refill with supermarket fuel and try again straight away.