Faced the same issue when I recently changed my thermostat.
Took the opportunity for a good flushing session with a hosepipe stuck in every possible hose end, at the end of which I was reasonably confident that the 4 1/2 litres approx of fluid content that does not drain down was clean water.
Rightly or wrongly I reasoned that adding another 4 1/2 litrs fluid of a 50/50 mix would eventually result in only a 25% strength mixture, so I took the step of adding 5 litres of pure coolant straight into the header tank.
After warming up and a bit of burping I topped off with roughly 1/2 litre of clean water, put the cap on and ran it up to full fan-on temperature. Visually at least the fluid seems to quickly blend into the correct mix. Not ideal perhaps but short of taking the water pump out couldn't think what else to do.
Steve